This was the first time I've ever heard of a visa electron card.
I'm not sure what you're asking though. From what I've read (did some quick research before responding), Visa Electron can be used anywhere Visa is accepted to make payments. Do you want to make payments to a US company with it (for products or whatever), or do you want to be paid by a US company via the card?
If you just want to make a payment, it should work as long as the company accepts Visa.
The US is just starting to implement Visa Electron type cards. There is a few different Payroll cards out there carrying either the Mastercard or Visa logos, and things like that. For some reason, we Americans seem to like carrying the green stuff... :P Cold Hard Cash! As time goes on though, we're going more and more digital. So we'll probably be doing the Visa Electron thing within a few years.